By Peter Urben
Bretherick's guide of Reactive Chemical dangers is extensively considered as the reference paintings during this box - an meeting of all pronounced hazards corresponding to explosion, fireplace, poisonous or high-energy occasions that consequence from chemical reactions long gone off target, with large referencing to the first literature. it truly is designed to enhance security in laboratories that practice chemical synthesis and normal examine, in addition to chemical production crops. Entries are ordered via empirical formulation and listed lower than either name(s) and Chemical Abstracts Registry Numbers. This two-volume compendium specializes in reactivity hazards of chemical compounds, on my own and together; toxicity risks are just integrated for unforeseen reactions giving risky poisons.The 2-volume set is obtainable on an introductory fee of $320/?270/??185 till Jan 2007. Will then revert to the checklist expense of $395/?330/??230. Order your replica on the introductory rate now. * expect, keep away from, and keep watch over reactivity risk with this most up-to-date version of the major advisor * Covers each chemical with documented details on reactive risks; greater than 5,000 entries on unmarried components or compounds, and 5,000 entries at the interactions among or extra compounds * contains 5 years of latest stories, new references to the first literature, and amplification to latest entries* hyperlinks related compounds or incidents that aren't evidently similar
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Additional resources for Bretherick's Handbook of Reactive Chemical Hazards, Seventh Edition (Two Volume Set)
1949, 71, 2950 The vapour is spontaneously flammable in air , and explodes in oxygen, but only in presence of traces of moisture .
Sci. , 1966, 10, 336 Aqueous silver nitrate reacts with acetaldehyde to give explosive silver fulminate. Acetylene and derivatives Mellor, 1946, Vol. 5, 854 Silver nitrate (or other soluble salt) reacts with acetylene in presence of ammonia to form silver acetylide, a sensitive and powerful detonator when dry. In the absence of 9 ammonia, or when calcium acetylide is added to silver nitrate solution, explosive double salts of silver acetylide and silver nitrate are produced. Mercury(I) acetylide precipitates silver acetylide from the aqueous nitrate.
Org. , 1962, 27, 4663 2. MCA Case History No. 1554 3. Morse, J. , School Sci. , 1955, 37(131), 147 4. , School Sci. , 1967, 48(165), 586 10 AgNO3 5. MacWilliam, E. A. , Photogr. Sci. , 1977, 21, 221—224 6. , Univ. Safety Assoc. Safety News, 1977, (8), 15—16 During preparation of an oxidising agent on a larger scale than described , addition of warm sodium hydroxide solution to warm ammoniacal silver nitrate with stirring caused immediate precipitation of black silver nitride which exploded .
Bretherick's Handbook of Reactive Chemical Hazards, Seventh Edition (Two Volume Set) by Peter Urben